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  1. 118 総合文化研究科・教養学部
  2. 50 広域科学専攻
  3. 1185010 学術雑誌論文
  1. 0 資料タイプ別
  2. 10 学術雑誌論文
  3. 014 自然科学

Induced-fit expansion and contraction of a self-assembled nanocube finely responding to neutral and anionic guests

http://hdl.handle.net/2261/00076470
http://hdl.handle.net/2261/00076470
c8cc22af-9ea9-4793-b769-69e215e693d1
名前 / ファイル ライセンス アクション
ncomms4530.pdf ncomms4530.pdf (1.3 MB)
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Item type 学術雑誌論文 / Journal Article(1)
公開日 2018-12-12
タイトル
タイトル Induced-fit expansion and contraction of a self-assembled nanocube finely responding to neutral and anionic guests
言語
言語 eng
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Zhan, Yi-Yang

× Zhan, Yi-Yang

WEKO 152975

Zhan, Yi-Yang

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Kojima, Tatsuo

× Kojima, Tatsuo

WEKO 152976

Kojima, Tatsuo

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Nakamura, Takashi

× Nakamura, Takashi

WEKO 152977

Nakamura, Takashi

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Takahashi, Toshihiro

× Takahashi, Toshihiro

WEKO 152978

Takahashi, Toshihiro

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Takahashi, Satoshi

× Takahashi, Satoshi

WEKO 152979

Takahashi, Satoshi

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Haketa, Yohei

× Haketa, Yohei

WEKO 152980

Haketa, Yohei

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Shoji, Yoshiaki

× Shoji, Yoshiaki

WEKO 152981

Shoji, Yoshiaki

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Maeda, Hiromitsu

× Maeda, Hiromitsu

WEKO 152982

Maeda, Hiromitsu

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Fukushima, Takanori

× Fukushima, Takanori

WEKO 152983

Fukushima, Takanori

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Hiraoka, Shuichi

× Hiraoka, Shuichi

WEKO 152984

Hiraoka, Shuichi

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著者所属
著者所属 Department of Basic Science, Graduate School of Arts and Sciences, The University of Tokyo
著者所属
著者所属 Department of Applied Chemistry, College of Life Sciences, Ritsumeikan University
著者所属
著者所属 Laboratory for Chemistry and Life Science, Institute of Innovative Research, Tokyo Institute of Technology
抄録
内容記述タイプ Abstract
内容記述 Induced-fit or conformational selection is of profound significance in biological regulation. Biological receptors alter their conformation to respond to the shape and electrostatic surfaces of guest molecules. Here we report a water-soluble artificial molecular host that can sensitively respond to the size, shape, and charged state of guest molecules. The molecular host, i.e. nanocube, is an assembled structure consisting of six gear-shaped amphiphiles (GSAs). This nanocube can expand or contract its size upon the encapsulation of neutral and anionic guest molecules with a volume ranging from 74 to 535 Å3 by induced-fit. The responding property of this nanocube, reminiscent of a feature of biological molecules, arises from the fact that the GSAs in the nanocubes are connected to each other only through the hydrophobic effect and very weak intermolecular interactions such as van der Waals and cation-π interactions.
内容記述
内容記述タイプ Other
内容記述 UTokyo FOCUS Press releases掲載「取り込む分子の大きさ・形・電荷に応答して膨らんだり縮んだりする分子カプセル」<研究成果> URI: https://www.u-tokyo.ac.jp/focus/ja/press/z0109_00048.html
内容記述
内容記述タイプ Other
内容記述 UTokyo FOCUS Press releases "Don’t underestimate the Force Researchers discover weak chemical interactions hold together box of infinite possibilities"<Research news> URI: https://www.u-tokyo.ac.jp/focus/en/press/z0508_00014.html
書誌情報 Nature communications

巻 9, p. 4530, 発行日 2018-10-31
ISSN
収録物識別子タイプ ISSN
収録物識別子 2041-1723
DOI
識別子タイプ DOI
関連識別子 info:doi/10.1038/s41467-018-06874-y
権利
権利情報 © The Author(s) 2018. This article is licensed under a Creative Commons Attribution 4.0 International License, which permits use, sharing, adaptation, distribution and reproduction in any medium or format, as long as you give appropriate credit to the original author(s) and the source, provide a link to the Creative Commons license, and indicate if changes were made. The images or other third party material in this article are included in the article’s Creative Commons license, unless indicated otherwise in a credit line to the material. If material is not included in the article’s Creative Commons license and your intended use is not permitted by statutory regulation or exceeds the permitted use, you will need to obtain permission directly from the copyright holder. To view a copy of this license, visit http://creativecommons.org/licenses/by/4.0/.
著者版フラグ
値 publisher
出版者
出版者 Springer Nature
関係URI
識別子タイプ URI
関連識別子 https://www.u-tokyo.ac.jp/focus/ja/press/z0109_00048.html
関係URI
識別子タイプ URI
関連識別子 https://www.u-tokyo.ac.jp/focus/en/press/z0508_00014.html
関係URI
識別子タイプ DOI
関連識別子 https://doi.org/10.1038/s41467-018-06874-y
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