{"created":"2023-06-20T07:14:42.134832+00:00","id":2007598,"links":{},"metadata":{"_buckets":{"deposit":"ec87b5f4-fcc6-48a9-9226-809753b56165"},"_deposit":{"created_by":18,"id":"2007598","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"2007598"},"status":"published"},"_oai":{"id":"oai:repository.dl.itc.u-tokyo.ac.jp:02007598","sets":["6:18:19","9:10:11"]},"author_link":[],"control_number":"2007598","item_1623051606154":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_type":"AM"}]},"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-04-21","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"9","bibliographicPageEnd":"1066","bibliographicPageStart":"1063","bibliographicVolumeNumber":"41","bibliographic_titles":[{"bibliographic_title":"Organometallics","bibliographic_titleLang":"en"}]}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"We here report the oxidative addition of a hydroborane ligand to two low-valent Ir(I) precursors to furnish Ir(III) hydride complexes bearing a bidentate boryl/phosphine ligand. One cationic iridium complex easily displaces a THF and 1,5-COD supporting ligand by hydrogenation in benzene, to form a stable Ir(III) η⁶-benzene complex. The arene coordination thus gives insight into possible poisoning by arenes in catalytic reactions.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_2_publisher_20":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_2_relation_25":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.organomet.2c00126","subitem_relation_type_select":"URI"}}]},"item_2_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright [© 2022 American Chemical Society] after peer review and technical editing by the publisher. To access the final edited and published work see [https://doi.org/10.1021/acs.organomet.2c00126]."}]},"item_2_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"02767333","subitem_source_identifier_type":"PISSN"}]},"item_2_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"The University of Tokyo","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Seidel, Falk William","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"0000-0001-6450-7829","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0001-6450-7829"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"The University of Tokyo","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Nozaki, Kyoko","creatorNameLang":"en"}],"nameIdentifiers":[{"nameIdentifier":"0000-0002-0321-5299","nameIdentifierScheme":"ORCID","nameIdentifierURI":"https://orcid.org/0000-0002-0321-5299"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2023-06-20"}],"displaytype":"detail","filename":"acs_organomet2c00126.pdf","filesize":[{"value":"476.4 KB"}],"format":"application/pdf","license_note":"© 2022 American Chemical Society","licensetype":"license_note","mimetype":"application/pdf","url":{"objectType":"fulltext","url":"https://repository.dl.itc.u-tokyo.ac.jp/record/2007598/files/acs_organomet2c00126.pdf"},"version_id":"c03917fc-a630-4772-8905-1b42cc49b407"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand","subitem_title_language":"en"}]},"item_type_id":"2","owner":"18","path":["11","19"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2023-06-20"},"publish_date":"2023-06-20","publish_status":"0","recid":"2007598","relation_version_is_last":true,"title":["Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2023-06-20T07:21:55.458531+00:00"}