{"created":"2024-02-08T00:58:58.589022+00:00","id":2008374,"links":{},"metadata":{"_buckets":{"deposit":"776513da-acc4-4129-868f-52d33c56bb48"},"_deposit":{"created_by":18,"id":"2008374","owner":"18","owners":[18],"pid":{"revision_id":0,"type":"depid","value":"2008374"},"status":"published"},"_oai":{"id":"oai:repository.dl.itc.u-tokyo.ac.jp:02008374","sets":["6:18:19","9:10:11"]},"author_link":[],"control_number":"2008374","item_1623051606154":{"attribute_name":"出版タイプ","attribute_value_mlt":[{"subitem_version_resource":"http://purl.org/coar/version/c_ab4af688f83e57aa","subitem_version_type":"AM"}]},"item_2_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2022-09-08","bibliographicIssueDateType":"Issued"},"bibliographicIssueNumber":"19","bibliographicPageEnd":"12740","bibliographicPageStart":"12733","bibliographicVolumeNumber":"87","bibliographic_titles":[{"bibliographic_title":"The Journal of Organic Chemistry","bibliographic_titleLang":"en"}]}]},"item_2_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"2,2,6,6-Tetramethylpiperidine-N-oxyl (TEMPO) has been extensively utilized as a radical scavenger or an oxidation catalyst. In contrast, TEMPO as a hydrogen atom transfer (HAT) catalyst has rarely been studied. Here, we report that TEMPO, as the HAT catalyst, homolytically cleaves benzylic or allylic C–H bonds to give the corresponding alkyl radicals. Benefiting from the dual roles played by TEMPO as the HAT catalyst and the radical scavenger, the highly challenging aerobic dehydrogenation of activated alkanes to alkenes is successfully developed.","subitem_description_language":"en","subitem_description_type":"Abstract"}]},"item_2_publisher_20":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"American Chemical Society","subitem_publisher_language":"en"}]},"item_2_relation_25":{"attribute_name":"関係URI","attribute_value_mlt":[{"subitem_relation_type":"isVersionOf","subitem_relation_type_id":{"subitem_relation_type_id_text":"https://doi.org/10.1021/acs.joc.2c01302","subitem_relation_type_select":"URI"}}]},"item_2_rights_12":{"attribute_name":"権利","attribute_value_mlt":[{"subitem_rights":"This document is the Accepted Manuscript version of a Published Work that appeared in final form in [The Journal of Organic Chemistry], copyright [© 2022 American Chemical Society] after peer review and technical editing by the publisher. To access the final edited and published work see [https://doi.org/10.1021/acs.joc.2c01302].","subitem_rights_language":"en"}]},"item_2_source_id_8":{"attribute_name":"ISSN","attribute_value_mlt":[{"subitem_source_identifier":"0022-3263","subitem_source_identifier_type":"PISSN"},{"subitem_source_identifier":"1520-6904","subitem_source_identifier_type":"EISSN"}]},"item_2_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_language":"en","subitem_text_value":"Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"The University of Tokyo","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Ito, Tasuku","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"The University of Tokyo","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Seidel, Falk William","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"The University of Tokyo","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Jin, Xiongjie","creatorNameLang":"en"}]},{"creatorAffiliations":[{"affiliationNames":[{"affiliationName":"The University of Tokyo","affiliationNameLang":"en"}]}],"creatorNames":[{"creatorName":"Nozaki, Kyoko","creatorNameLang":"en"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_access","date":[{"dateType":"Available","dateValue":"2024-02-08"}],"displaytype":"detail","filename":"TEMPO_as_a_Hydrogen_Atom_Transfer.pdf","filesize":[{"value":"685 KB"}],"format":"application/pdf","license_note":"© 2022 American Chemical Society","licensetype":"license_note","mimetype":"application/pdf","url":{"url":"https://repository.dl.itc.u-tokyo.ac.jp/record/2008374/files/TEMPO_as_a_Hydrogen_Atom_Transfer.pdf"},"version_id":"3fcc5eba-9fd9-41d7-92de-739ab27ed1c2"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"journal article","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes","subitem_title_language":"en"}]},"item_type_id":"2","owner":"18","path":["11","19"],"pubdate":{"attribute_name":"PubDate","attribute_value":"2024-02-08"},"publish_date":"2024-02-08","publish_status":"0","recid":"2008374","relation_version_is_last":true,"title":["TEMPO as a Hydrogen Atom Transfer Catalyst for Aerobic Dehydrogenation of Activated Alkanes to Alkenes"],"weko_creator_id":"18","weko_shared_id":-1},"updated":"2024-02-08T01:26:10.389831+00:00"}