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The configurations of complexes [Co(NH3)5C2O4X], [Co(NH3)5CO3X], [Co(NH3)5SO4X] and [Co(NH3)5SO3X] have been determined. 2. The theory of the maximum coordination number has been discussed and the cubic configuration has been introduced for complexes of the type [Co(NH3)5X11X1]. 3. Optically active isomers have been obtained from [Co(NH3)5C2O4SO4H] and [Co(NH3)5SO4SO4H]. 4. The absorption spectra of the above mentioned substances have been measured and the results obtained have been discussed. 5. The view that strong acid radicles have the weakest coordination affinity has been verified by the measurements of the electrolytic conductivities of these salts. The author is indebted to Prof. Y. Shibata for his kind guidance and advice and also to Mr. K. 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On the Stereochemical Configurations of Cobalt Complexes with Anomalous Coordination Numbers
https://doi.org/10.15083/00037662
https://doi.org/10.15083/00037662d54093f2-8857-4be8-bb5f-ac83ee0e43b7
名前 / ファイル | ライセンス | アクション |
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jcs045008.pdf (748.7 kB)
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Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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公開日 | 2010-02-08 | |||||
タイトル | ||||||
タイトル | On the Stereochemical Configurations of Cobalt Complexes with Anomalous Coordination Numbers | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | departmental bulletin paper | |||||
ID登録 | ||||||
ID登録 | 10.15083/00037662 | |||||
ID登録タイプ | JaLC | |||||
著者 |
MATSUNO, Kichimatsu
× MATSUNO, Kichimatsu |
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著者所属 | ||||||
著者所属 | The Laboratory of Inorganic Chemistry, Faculty of Science, Imperial University of Tokyo | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | 1. The configurations of complexes [Co(NH3)5C2O4X], [Co(NH3)5CO3X], [Co(NH3)5SO4X] and [Co(NH3)5SO3X] have been determined. 2. The theory of the maximum coordination number has been discussed and the cubic configuration has been introduced for complexes of the type [Co(NH3)5X11X1]. 3. Optically active isomers have been obtained from [Co(NH3)5C2O4SO4H] and [Co(NH3)5SO4SO4H]. 4. The absorption spectra of the above mentioned substances have been measured and the results obtained have been discussed. 5. The view that strong acid radicles have the weakest coordination affinity has been verified by the measurements of the electrolytic conductivities of these salts. The author is indebted to Prof. Y. Shibata for his kind guidance and advice and also to Mr. K. Kobayashi, Rigakushi, for his assistance in measuring conductivities. | |||||
書誌情報 |
The Journal of the College of Science, Imperial University of Tokyo, Japan 巻 45, p. 1-16, 発行日 1925-07-07 |
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書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00695779 | |||||
書誌レコードID | ||||||
識別子タイプ | NCID | |||||
関連識別子 | BA29455243 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
日本十進分類法 | ||||||
主題 | 431.14 | |||||
主題Scheme | NDC | |||||
日本十進分類法 | ||||||
主題 | 436.82 | |||||
主題Scheme | NDC | |||||
出版者 | ||||||
出版者 | Inperial University of Tokyo | |||||
出版者別名 | ||||||
東京帝國大學理學部 |