{"created":"2021-03-01T06:56:56.249270+00:00","id":37671,"links":{},"metadata":{"_buckets":{"deposit":"9a77eddd-94a7-4d18-9d36-d62270bf2392"},"_deposit":{"id":"37671","owners":[],"pid":{"revision_id":0,"type":"depid","value":"37671"},"status":"published"},"_oai":{"id":"oai:repository.dl.itc.u-tokyo.ac.jp:00037671","sets":["75:5892:5893","9:504:5894:5895"]},"item_4_biblio_info_7":{"attribute_name":"書誌情報","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"1925-07-07","bibliographicIssueDateType":"Issued"},"bibliographicPageEnd":"16","bibliographicPageStart":"1","bibliographicVolumeNumber":"45","bibliographic_titles":[{"bibliographic_title":"The Journal of the College of Science, Imperial University of Tokyo, Japan"}]}]},"item_4_description_13":{"attribute_name":"フォーマット","attribute_value_mlt":[{"subitem_description":"application/pdf","subitem_description_type":"Other"}]},"item_4_description_5":{"attribute_name":"抄録","attribute_value_mlt":[{"subitem_description":"1. The configurations of complexes [Co(NH3)5C2O4X], [Co(NH3)5CO3X], [Co(NH3)5SO4X] and [Co(NH3)5SO3X] have been determined. 2. The theory of the maximum coordination number has been discussed and the cubic configuration has been introduced for complexes of the type [Co(NH3)5X11X1]. 3. Optically active isomers have been obtained from [Co(NH3)5C2O4SO4H] and [Co(NH3)5SO4SO4H]. 4. The absorption spectra of the above mentioned substances have been measured and the results obtained have been discussed. 5. The view that strong acid radicles have the weakest coordination affinity has been verified by the measurements of the electrolytic conductivities of these salts. The author is indebted to Prof. Y. Shibata for his kind guidance and advice and also to Mr. K. Kobayashi, Rigakushi, for his assistance in measuring conductivities.","subitem_description_type":"Abstract"}]},"item_4_identifier_registration":{"attribute_name":"ID登録","attribute_value_mlt":[{"subitem_identifier_reg_text":"10.15083/00037662","subitem_identifier_reg_type":"JaLC"}]},"item_4_publisher_20":{"attribute_name":"出版者","attribute_value_mlt":[{"subitem_publisher":"Inperial University of Tokyo"}]},"item_4_relation_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_relation_type_id":{"subitem_relation_type_id_text":"BA29455243","subitem_relation_type_select":"NCID"}}]},"item_4_source_id_10":{"attribute_name":"書誌レコードID","attribute_value_mlt":[{"subitem_source_identifier":"AA00695779","subitem_source_identifier_type":"NCID"}]},"item_4_subject_15":{"attribute_name":"日本十進分類法","attribute_value_mlt":[{"subitem_subject":"431.14","subitem_subject_scheme":"NDC"},{"subitem_subject":"436.82","subitem_subject_scheme":"NDC"}]},"item_4_text_21":{"attribute_name":"出版者別名","attribute_value_mlt":[{"subitem_text_value":"東京帝國大學理學部"}]},"item_4_text_4":{"attribute_name":"著者所属","attribute_value_mlt":[{"subitem_text_value":"The Laboratory of Inorganic Chemistry, Faculty of Science, Imperial University of Tokyo"}]},"item_creator":{"attribute_name":"著者","attribute_type":"creator","attribute_value_mlt":[{"creatorNames":[{"creatorName":"MATSUNO, Kichimatsu"}],"nameIdentifiers":[{"nameIdentifier":"136554","nameIdentifierScheme":"WEKO"}]}]},"item_files":{"attribute_name":"ファイル情報","attribute_type":"file","attribute_value_mlt":[{"accessrole":"open_date","date":[{"dateType":"Available","dateValue":"2017-06-27"}],"displaytype":"detail","filename":"jcs045008.pdf","filesize":[{"value":"748.7 kB"}],"format":"application/pdf","licensetype":"license_note","mimetype":"application/pdf","url":{"label":"jcs045008.pdf","url":"https://repository.dl.itc.u-tokyo.ac.jp/record/37671/files/jcs045008.pdf"},"version_id":"32bab7da-8367-44a3-b401-cdd87f6fd033"}]},"item_language":{"attribute_name":"言語","attribute_value_mlt":[{"subitem_language":"eng"}]},"item_resource_type":{"attribute_name":"資源タイプ","attribute_value_mlt":[{"resourcetype":"departmental bulletin paper","resourceuri":"http://purl.org/coar/resource_type/c_6501"}]},"item_title":"On the Stereochemical Configurations of Cobalt Complexes with Anomalous Coordination Numbers","item_titles":{"attribute_name":"タイトル","attribute_value_mlt":[{"subitem_title":"On the Stereochemical Configurations of Cobalt Complexes with Anomalous Coordination Numbers"}]},"item_type_id":"4","owner":"1","path":["5893","5895"],"pubdate":{"attribute_name":"公開日","attribute_value":"2010-02-08"},"publish_date":"2010-02-08","publish_status":"0","recid":"37671","relation_version_is_last":true,"title":["On the Stereochemical Configurations of Cobalt Complexes with Anomalous Coordination Numbers"],"weko_creator_id":"1","weko_shared_id":null},"updated":"2022-12-19T04:20:14.553942+00:00"}