{"created":"2021-03-01T06:22:11.573350+00:00","id":5495,"links":{},"metadata":{"_buckets":{"deposit":"b145ff37-8bb0-45bf-8ba9-95374e5f385d"},"_deposit":{"id":"5495","owners":[],"pid":{"revision_id":0,"type":"depid","value":"5495"},"status":"published"},"_oai":{"id":"oai:repository.dl.itc.u-tokyo.ac.jp:00005495"},"item_7_alternative_title_1":{"attribute_name":"\u305d\u306e\u4ed6\u306e\u30bf\u30a4\u30c8\u30eb","attribute_value_mlt":[{"subitem_alternative_title":"\u30d1\u30e9\u30b8\u30a6\u30e0\u89e6\u5a92\u3092\u7528\u3044\u305f\u6975\u6027\u30d3\u30cb\u30eb\u30e2\u30ce\u30de\u30fc\u3068\u4e00\u9178\u5316\u70ad\u7d20\u306e\u5171\u91cd\u5408"}]},"item_7_biblio_info_7":{"attribute_name":"\u66f8\u8a8c\u60c5\u5831","attribute_value_mlt":[{"bibliographicIssueDates":{"bibliographicIssueDate":"2012-03-22","bibliographicIssueDateType":"Issued"},"bibliographic_titles":[{}]}]},"item_7_date_granted_25":{"attribute_name":"\u5b66\u4f4d\u6388\u4e0e\u5e74\u6708\u65e5","attribute_value_mlt":[{"subitem_dategranted":"2012-03-22"}]},"item_7_degree_grantor_23":{"attribute_name":"\u5b66\u4f4d\u6388\u4e0e\u6a5f\u95a2","attribute_value_mlt":[{"subitem_degreegrantor":[{"subitem_degreegrantor_name":"University of Tokyo (\u6771\u4eac\u5927\u5b66)"}]}]},"item_7_degree_name_20":{"attribute_name":"\u5b66\u4f4d\u540d","attribute_value_mlt":[{"subitem_degreename":"\u535a\u58eb(\u5de5\u5b66)"}]},"item_7_description_5":{"attribute_name":"\u6284\u9332","attribute_value_mlt":[{"subitem_description":"Synthesis of novel polymers can offer us a chance to improve our quality of life. In this thesis, the author describes the first synthesis of \u03b3-polyketones directly functionalized with ester groups. These polymers were achieved by copolymerization of inexpensive petrochemicals, i.e., polar vinyl monomers and carbon monoxide. The catalyst employed for these reactions was a series of palladium phosphine-sulfonate complexes. In Chapter 1, motivation and detailed background of this work are explained. Then in Chapter 2, scope of the monomers is disclosed. In Chapters 3 and 4, the detailed structural analyses and the reaction mechanisms are described for methyl acrylate and vinyl acetate cases, respectively. Through the detailed study, the role of unique sulfonate group is analyzed. Next, the author shows the use of P-chiral phosphine-sulfonate ligand enables the microstructure regulation of the resulting \u03b3-polyketone (Chapter 5). In addition, terpolymerizations of polar vinyl monomers, carbon monoxide, and ethylene are also shown in Chapter 6. Finally, physical properties of these co- and terpolymers are investigated to reveal the effect of ester groups into \u03b3-polyketone. The research regarding this dissertation has been performed through 2006-2012 under the guidance of Prof. Kyoko Nozaki and supported by JSPS.","subitem_description_type":"Abstract"},{"subitem_description":"\u65b0\u305f\u306a\u9ad8\u5206\u5b50\u6750\u6599\u3092\u751f\u307f\u51fa\u3059\u3053\u3068\u306f\u3001\u6211\u3005\u306e\u751f\u6d3b\u3092\u8c4a\u304b\u306b\u3059\u308b\u305f\u3081\u306e\u91cd\u8981\u306a\u30a2\u30d7\u30ed\u30fc\u30c1\u3067\u3042\u308b\u3002\u672c\u535a\u58eb\u8ad6\u6587\u7814\u7a76\u3067\u306f\u3001\u76f4\u63a5\u30a8\u30b9\u30c6\u30eb\u57fa\u3067\u4fee\u98fe\u3055\u308c\u305f\u03b3-\u30dd\u30ea\u30b1\u30c8\u30f3\u306e\u5408\u6210\u306b\u521d\u3081\u3066\u6210\u529f\u3057\u305f\u3002\u3053\u306e\u30dd\u30ea\u30de\u30fc\u306f\u3001\u5b89\u4fa1\u306a\u77f3\u6cb9\u5316\u5b66\u88fd\u54c1\u3067\u3042\u308b\u6975\u6027\u30d3\u30cb\u30eb\u30e2\u30ce\u30de\u30fc\u3068\u4e00\u9178\u5316\u70ad\u7d20\u306e\u5171\u91cd\u5408\u53cd\u5fdc\u306b\u3088\u3063\u3066\u5f97\u3089\u308c\u305f\u3002\u3053\u306e\u53cd\u5fdc\u306f\u3001\u30d1\u30e9\u30b8\u30a6\u30e0\uff0f\u30db\u30b9\u30d5\u30a3\u30f3\uff0d\u30b9\u30eb\u30db\u30ca\u30fc\u30c8\u914d\u4f4d\u5b50\u7cfb\u306e\u932f\u4f53\u3092\u3001\u89e6\u5a92\u3068\u3057\u3066\u7528\u3044\u308b\u3053\u3068\u304c\u9375\u3067\u3042\u3063\u305f\u3002\u7b2c1\u7ae0\u3067\u306f\u3001\u672c\u7814\u7a76\u306e\u52d5\u6a5f\u3068\u80cc\u666f\u306b\u3064\u3044\u3066\u8a73\u7d30\u306b\u8aac\u660e\u3059\u308b\u3002\u6b21\u306b\u7b2c2\u7ae0\u3067\u30e2\u30ce\u30de\u30fc\u306e\u9069\u7528\u7bc4\u56f2\u306b\u3064\u3044\u3066\u8ff0\u3079\u308b\u3002\u7b2c3\u7ae0\u3068\u7b2c4\u7ae0\u3067\u306f\u3001\u305d\u308c\u305e\u308c\u30a2\u30af\u30ea\u30eb\u9178\u30e1\u30c1\u30eb\u3068\u9162\u9178\u30d3\u30cb\u30eb\u3092\u7528\u3044\u305f\u5834\u5408\u306b\u3064\u3044\u3066\u3001\u30dd\u30ea\u30de\u30fc\u306e\u69cb\u9020\u89e3\u6790\u3068\u53cd\u5fdc\u6a5f\u69cb\u3092\u8abf\u3079\u308b\u3002\u3053\u308c\u3089\u306e\u7ae0\u3092\u901a\u3057\u3066\u3001\u672c\u89e6\u5a92\u306e\u7279\u5fb4\u3067\u3042\u308b\u30b9\u30eb\u30db\u30ca\u30fc\u30c8\u90e8\u4f4d\u306e\u5f79\u5272\u306b\u3064\u3044\u3066\u8003\u5bdf\u3059\u308b\u3002\u7d9a\u3044\u3066\u3001P-\u30ad\u30e9\u30eb\u306a\u914d\u4f4d\u5b50\u3092\u7528\u3044\u308b\u3053\u3068\u3067\u5171\u91cd\u5408\u4f53\u306e\u4e00\u6b21\u69cb\u9020\u304c\u5236\u5fa1\u53ef\u80fd\u3067\u3042\u308b\u3053\u3068\u3092\u793a\u3059(\u7b2c5\u7ae0)\u3002\u3055\u3089\u306b\u6975\u6027\u30d3\u30cb\u30eb\u30e2\u30ce\u30de\u30fc\u30fb\u4e00\u9178\u5316\u70ad\u7d20\u30fb\u30a8\u30c1\u30ec\u30f3\u306e\u4e09\u5143\u5171\u91cd\u5408\u306b\u3082\u8a00\u53ca\u3057(\u7b2c6\u7ae0)\u3001\u7b2c7\u7ae0\u3067\u3053\u308c\u3089\u30a8\u30b9\u30c6\u30eb\u7f6e\u63db\u30dd\u30ea\u30b1\u30c8\u30f3\u306e\u7269\u6027\u89e3\u6790\u7d50\u679c\u3092\u793a\u3059\u3002\u3053\u306e\u535a\u58eb\u8ad6\u6587\u306b\u95a2\u3059\u308b\u7814\u7a76\u306f\u30012006\u5e74\u304b\u30892012\u5e74\u306b\u304b\u3051\u3066\u3001\u91ce\u5d0e\u4eac\u5b50\u6559\u6388\u306e\u3054\u6307\u5c0e\u306e\u3082\u3068\u3001\u65e5\u672c\u5b66\u8853\u632f\u8208\u4f1a\u306e\u652f\u63f4\u3092\u5f97\u3066\u884c\u308f\u308c\u305f\u3002","subitem_description_type":"Abstract"}]},"item_7_dissertation_number_26":{"attribute_name":"\u5b66\u4f4d\u6388\u4e0e\u756a\u53f7","attribute_value_mlt":[{"subitem_dissertationnumber":"\u7532\u7b2c27995\u53f7"}]},"item_7_full_name_3":{"attribute_name":"\u8457\u8005\u5225\u540d","attribute_value_mlt":[{"nameIdentifiers":[{"nameIdentifier":"11448","nameIdentifierScheme":"WEKO"}],"names":[{"name":"\u4e2d\u6751, 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