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研究速報 : p-ベンゾキノン類とジアゾメタン類との成環付加反応およびその成環付加体と塩基との反応
http://hdl.handle.net/2261/53379
a602fc45-7783-45f2-9a10-53fbf58c3aa5
| 名前 / ファイル | ライセンス | アクション | |
|---|---|---|---|
sk050008005.pdf (685.3 kB)
|
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2013-03-08 | |||||
| タイトル | ||||||
| タイトル | 研究速報 : p-ベンゾキノン類とジアゾメタン類との成環付加反応およびその成環付加体と塩基との反応 | |||||
| 言語 | ||||||
| 言語 | jpn | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| その他のタイトル | ||||||
| その他のタイトル | 1, 3-Dipolar Cycloaddition of p-Benzoquinones with Diazomethanes and the Reaction of the Cycloadducts with Base | |||||
| 著者 |
務川, 高志
× 務川, 高志× 伏見, 邦彦× 工藤, 一秋× 白石, 振作 |
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| 著者別名 | ||||||
| 識別子 | ||||||
| 識別子 | 30139 | |||||
| 識別子Scheme | WEKO | |||||
| 姓名 | ||||||
| 姓名 | Mukawa, Takashi | |||||
| 著者別名 | ||||||
| 識別子 | ||||||
| 識別子 | 30140 | |||||
| 識別子Scheme | WEKO | |||||
| 姓名 | ||||||
| 姓名 | Fushimi, Kunihiko | |||||
| 著者別名 | ||||||
| 識別子 | ||||||
| 識別子 | 30141 | |||||
| 識別子Scheme | WEKO | |||||
| 姓名 | ||||||
| 姓名 | Kudo, Kazuaki | |||||
| 著者別名 | ||||||
| 識別子 | ||||||
| 識別子 | 30142 | |||||
| 識別子Scheme | WEKO | |||||
| 姓名 | ||||||
| 姓名 | Shiraishi, Shinsaku | |||||
| 著者所属 | ||||||
| 東京大学生産技術研究所第4部 有機合成化学 | ||||||
| 著者所属 | ||||||
| 特許庁 | ||||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | p-ベンゾキノン類とジアゾメタン類の1, 3-双極成環付加反応について検討したところ, ジフェニルジアゾメタンからは脱窒素したシクロプロパン誘導体が得られた. トリメチルシリルジアゾメタンを用いると, 1, 3-双極成環付加体のトリメチルシリル基の付け根の水素が窒素上に移動した生成物が得られた. 2, 5-ジ-tert-ブチル-p-ベンゾキノンとトリメチルシリルジアゾメタンとの成環付加体に水酸化ナトリウムを加えると橋頭位のtert-ブチル基が隣のカルボニル炭素に転位した異性体が得られた. | |||||
| 書誌情報 |
生産研究 巻 50, 号 8, p. 274-277, 発行日 1998-08 |
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| ISSN | ||||||
| 収録物識別子タイプ | ISSN | |||||
| 収録物識別子 | 0037105X | |||||
| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AN00127075 | |||||
| 日本十進分類法 | ||||||
| 主題 | 437 | |||||
| 主題Scheme | NDC | |||||
| 出版者 | ||||||
| 出版者 | 東京大学生産技術研究所 | |||||
| 出版者別名 | ||||||
| Institute of Industrial Science, the University of Tokyo | ||||||
