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A Ni⁰ σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization
http://hdl.handle.net/2261/0002007594
http://hdl.handle.net/2261/00020075941cb99f9b-129c-476e-bd92-dc29f5fc3a37
| 名前 / ファイル | ライセンス | アクション |
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anie202111691.pdf (1.5 MB)
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© 2021 Wiley-VCH GmbH
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2023-06-20 | |||||
| タイトル | ||||||
| タイトル | A Ni⁰ σ-Borane Complex Bearing a Rigid Bidentate Borane/Phosphine Ligand: Boryl Complex Formation by Oxidative Dehydrochloroborylation and Catalytic Activity for Ethylene Polymerization | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 著者 |
Seidel, Falk William
× Seidel, Falk William× Nozaki, Kyoko |
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| 著者所属 | ||||||
| 言語 | en | |||||
| 著者所属 | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | While of interest, synthetically feasible access to boryl ligands and complexes remains limited, meaning such complexes remain underexploited in catalysis. For bidentate boryl ligands, oxidative addition of boranes to low-valent IrI or Pt⁰ are the only examples yet reported. As part of our interest in developing improved group 10 ethylene polymerization catalysts, we present here an optimized synthesis of a novel, rigid borane/phosphine ligand and its Ni⁰ σ-borane complex. From the latter, an unprecedented oxidative dehydrochloroborylation, to give a Ni^II boryl complex, was achieved. Furthermore, this new B/P ligand allowed the nickel-catalyzed polymerization of ethylene, which suggests that Ni⁰ σ-hydroborane complexes act as masked Ni^II boryl hydride reagents. | |||||
| 言語 | en | |||||
| 書誌情報 |
en : Angewandte Chemie International Edition 巻 61, 号 6, p. e202111691, 発行日 2021-12-01 |
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| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 14337851 | |||||
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| 収録物識別子タイプ | EISSN | |||||
| 収録物識別子 | 15213773 | |||||
| 権利 | ||||||
| 権利情報 | This is the peer reviewed version of the following article: [F. W. Seidel, K. Nozaki, Angew. Chem. Int. Ed. 2022, 61, e202111691.], which has been published in final form at [https://doi.org/10.1002/anie.202111691]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
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| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://doi.org/10.1002/anie.202111691 | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
