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Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O₂ Oxidation
http://hdl.handle.net/2261/0002007595
http://hdl.handle.net/2261/00020075955efc9dbf-f321-4e18-b85d-d78580253304
| 名前 / ファイル | ライセンス | アクション |
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anie202117096.pdf (1.1 MB)
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© 2022 Wiley-VCH GmbH
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2023-06-20 | |||||
| タイトル | ||||||
| タイトル | Atom Swapping on Aromatic Rings: Conversion from Phosphinine Pincer Metal Complexes to Metallabenzenes Triggered by O₂ Oxidation | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 著者 |
Masada, Koichiro
× Masada, Koichiro× Kusumoto, Shuhei× Nozaki, Kyoko |
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| 著者所属 | ||||||
| 言語 | en | |||||
| 著者所属 | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | Herein, we report a novel method for the synthesis of metallabenzenes by swapping the phosphorus atom in an aromatic phosphinine ring with transition metal fragments. The oxidation of a phosphine-phosphinine-phosphine pincer iridium complex by O2 triggered the replacement of the phosphorus atom of the phosphinine ring by an iridium fragment to afford iridabenzene. Dianionic rhodabenzene was also synthesized from a phosphinine rhodium complex by oxidation of the phosphorus atom, followed by subsequent reduction using metallic potassium. The aromaticity of the newly synthesized irida- and rhoda-benzenes was evaluated both experimentally and theoretically. | |||||
| 言語 | en | |||||
| 書誌情報 |
en : Angewandte Chemie International Edition 巻 61, 号 21, p. e202117096, 発行日 2022-02-21 |
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| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 14337851 | |||||
| ISSN | ||||||
| 収録物識別子タイプ | EISSN | |||||
| 収録物識別子 | 15213773 | |||||
| 権利 | ||||||
| 権利情報 | This is the peer reviewed version of the following article: [K. Masada, S. Kusumoto, K. Nozaki, Angew. Chem. Int. Ed. 2022, 61, e202117096], which has been published in final form at [https://doi.org/10.1002/anie.202117096]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. This article may not be enhanced, enriched or otherwise transformed into a derivative work, without express permission from Wiley or by statutory rights under applicable legislation. Copyright notices must not be removed, obscured or modified. The article must be linked to Wiley’s version of record on Wiley Online Library and any embedding, framing or otherwise making available the article or pages thereof by third parties from platforms, services and websites other than Wiley Online Library must be prohibited. | |||||
| 出版者 | ||||||
| 出版者 | Wiley | |||||
| 言語 | en | |||||
| 関係URI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://doi.org/10.1002/anie.202117096 | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
