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アイテム
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1,3-Dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP): a powerful condensing reagent for phosphate and phosphonate esters
http://hdl.handle.net/2261/3991
e1ccef8c-5291-47aa-8a7a-59c3d803f1cc
Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2007-01-10 | |||||
タイトル | ||||||
タイトル | 1,3-Dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP): a powerful condensing reagent for phosphate and phosphonate esters | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Phosphonium-type condensing reagent | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Phosphate | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Alkylphosphonate | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Boranophosphate | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | H-phosphonate | |||||
主題Scheme | Other | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
アクセス権 | ||||||
アクセス権 | metadata only access | |||||
アクセス権URI | http://purl.org/coar/access_right/c_14cb | |||||
著者 |
Wada, Takeshi
× Wada, Takeshi× Oka, Natsuhisa× Shimizu, Mamoru× Saigo, Kazuhiko |
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著者別名 | ||||||
識別子 | ||||||
識別子 | 160 | |||||
識別子Scheme | WEKO | |||||
姓名 | ||||||
姓名 | 西郷, 和彦 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | A novel phosphonium-type condensing reagent, 1,3-dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP), was designed and synthesized. A 31P NMR study on the condensation reactions of phosphate, alkylphosphonate, boranophosphate, and H-phosphonate derivatives with an alcohol in the presence of MNTP demonstrated the versatility and the enhanced activity of the new condensing reagent, compared to the previously reported phosphonium-type condensing reagents. The mechanism of the condensation reactions mediated by MNTP is discussed on the basis of the 31P NMR studies and theoretical calculations. | |||||
書誌情報 |
Tetrahedron 巻 62, 号 15, p. 3667-3673, 発行日 2006-04-10 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00404020 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00861787 | |||||
DOI | ||||||
関連識別子 | ||||||
識別子タイプ | DOI | |||||
関連識別子 | info:doi/10.1016/j.tet.2006.01.084 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
著者版フラグ | ||||||
値 | author | |||||
出版者 | ||||||
出版者 | Elsevier | |||||
関係URI | ||||||
関連識別子 | ||||||
識別子タイプ | URI | |||||
関連識別子 | http://www.sciencedirect.com/science/journal/00404020 |