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  1. 113 工学系研究科・工学部
  2. 40 化学生命工学専攻
  3. 1134010 学術雑誌論文
  1. 0 資料タイプ別
  2. 10 学術雑誌論文
  3. 014 自然科学

1,3-Dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP): a powerful condensing reagent for phosphate and phosphonate esters

http://hdl.handle.net/2261/3991
e1ccef8c-5291-47aa-8a7a-59c3d803f1cc
Item type 学術雑誌論文 / Journal Article(1)
公開日 2007-01-10
タイトル
タイトル 1,3-Dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP): a powerful condensing reagent for phosphate and phosphonate esters
言語
言語 eng
キーワード
主題 Phosphonium-type condensing reagent
主題Scheme Other
キーワード
主題 Phosphate
主題Scheme Other
キーワード
主題 Alkylphosphonate
主題Scheme Other
キーワード
主題 Boranophosphate
主題Scheme Other
キーワード
主題 H-phosphonate
主題Scheme Other
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
アクセス権
アクセス権 metadata only access
アクセス権URI http://purl.org/coar/access_right/c_14cb
著者 Wada, Takeshi

× Wada, Takeshi

WEKO 156

Wada, Takeshi

Search repository
Oka, Natsuhisa

× Oka, Natsuhisa

WEKO 157

Oka, Natsuhisa

Search repository
Shimizu, Mamoru

× Shimizu, Mamoru

WEKO 158

Shimizu, Mamoru

Search repository
Saigo, Kazuhiko

× Saigo, Kazuhiko

WEKO 159

Saigo, Kazuhiko

Search repository
著者別名
識別子
識別子 160
識別子Scheme WEKO
姓名
姓名 西郷, 和彦
抄録
内容記述タイプ Abstract
内容記述 A novel phosphonium-type condensing reagent, 1,3-dimethyl-2-(3-nitro-1,2,4-triazol-1-yl)-2-pyrrolidin-1-yl-1,3,2-diazaphospholidinium hexafluorophosphate (MNTP), was designed and synthesized. A 31P NMR study on the condensation reactions of phosphate, alkylphosphonate, boranophosphate, and H-phosphonate derivatives with an alcohol in the presence of MNTP demonstrated the versatility and the enhanced activity of the new condensing reagent, compared to the previously reported phosphonium-type condensing reagents. The mechanism of the condensation reactions mediated by MNTP is discussed on the basis of the 31P NMR studies and theoretical calculations.
書誌情報 Tetrahedron

巻 62, 号 15, p. 3667-3673, 発行日 2006-04-10
ISSN
収録物識別子タイプ ISSN
収録物識別子 00404020
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00861787
DOI
関連識別子
識別子タイプ DOI
関連識別子 info:doi/10.1016/j.tet.2006.01.084
フォーマット
内容記述タイプ Other
内容記述 application/pdf
著者版フラグ
値 author
出版者
出版者 Elsevier
関係URI
関連識別子
識別子タイプ URI
関連識別子 http://www.sciencedirect.com/science/journal/00404020
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