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On the Stereochemical Configuration of the Aquotriammine and Diammine Cobalt Complex Salts
https://doi.org/10.15083/00037694
https://doi.org/10.15083/00037694b3fef5f4-cd52-4241-9c5b-34fe6e430754
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
jcs041010.pdf (1.1 MB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
|---|---|---|---|---|---|---|
| 公開日 | 2010-02-07 | |||||
| タイトル | ||||||
| タイトル | On the Stereochemical Configuration of the Aquotriammine and Diammine Cobalt Complex Salts | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.15083/00037694 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
MATSUNO, Kichimatsu
× MATSUNO, Kichimatsu |
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| 著者所属 | ||||||
| 著者所属 | The Laboratyro of Inorganic Chemistry, the College of Science, Imperial university of Tokyo | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | 1. I have measured the absorption spectra of the aquocobaltammines and thereby demonstrated the influence of the coordinated water molecules. 2. The stereochemical configurations of the following cobaltammines were thoroughly determined. [Co(NH3)3Cl2H2O]X, [Co(NH3)3Cl(H2O)2]X2, [Co(NH3)3(H2O)3]X3, [Co(NH3)2Cl2(H2O2)X, [Co(HN3)2(H2O)3Cl]X2, [Co(NH3)3(NO3)3], [Co(NH3)4(H2O)2]X3, [Co(NH3)4ClH2O]X2 [Co(NH3)3C2O4NO3] 3. The following two new cobalt complex salts were produced. (1) Trans [Co(NH3)3(H2O)3]Cl3 (2) [CO(NH3)3C2O4NO3] 4. The formula [Co(NH3)3C2O4(H2O)2]NO3, which was given by Werner, must be amended to [Co(NH3)3C2O4NO3]H2O. 5. with regard to the substitution reactions of the cobaltammines which have radicals of the strong acids in the complex nucleus, a clear explanation has been given by the study of absorption of light and electrolytic conductivity. In conclusion, the author tenders his sincere thanks to Prof. Y. Shibata for his kind guidance and suggestions. | |||||
| 書誌情報 |
Journal of the College of Science, Imperial University of Tokyo 巻 41, p. 1-27, 発行日 1921-03-31 |
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| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00695779 | |||||
| 書誌レコードID | ||||||
| 識別子タイプ | NCID | |||||
| 関連識別子 | BA29455243 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 日本十進分類法 | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 431.14 | |||||
| 日本十進分類法 | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 436.82 | |||||
| 出版者 | ||||||
| 出版者 | Inperial University of Tokyo | |||||
| 出版者別名 | ||||||
| 東京帝國大學理學部 | ||||||
