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The Action of the Grignard Reagent on ο-Phthalic Esters
https://doi.org/10.15083/00037792
https://doi.org/10.15083/00037792518cd14b-1189-4eeb-9df0-36dcf3d79fc6
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
jcs027004.pdf (736.6 kB)
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| Item type | 紀要論文 / Departmental Bulletin Paper(1) | |||||
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| 公開日 | 2010-02-05 | |||||
| タイトル | ||||||
| タイトル | The Action of the Grignard Reagent on ο-Phthalic Esters | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | departmental bulletin paper | |||||
| ID登録 | ||||||
| ID登録 | 10.15083/00037792 | |||||
| ID登録タイプ | JaLC | |||||
| 著者 |
Shibata, Y.
× Shibata, Y. |
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| 著者所属 | ||||||
| 著者所属 | The Chemical Institute of the College of Science, Imperial University of Tokyo | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | 1. In spite of the great analogy existing between o-phthalic acid and succinic acid, the action of the Grignard reagent upon o-phthalic esters differs from that upon succinic esters in producing derivatives of phthalide, instead of producing glycols. 2. More frequently, the reaction between the Grignard reagent and o-phthalic esters goes even one step further, with production of the derivatives of phthalane. 1:1-Dimethyl-3-methylene-phthalane, 1:1-diphenyl-3-phenylene-phthalane and 1:1-dibenzyl-3-benzal-phthalane have thus been obtained and described. 3. Various space formulae proposed for benzene are discussed from the point of view of the experimental results obtained in this investigation, and it is shown that GRAEBE'S model, which represents KEKULE'S well known formula in space, accounts for the facts in the most satisfactory manner. In conclusion, I desire to express my best thanks to Professor MATSUBARA for his kind guidance and suggestions. | |||||
| 書誌情報 |
The journal of the College of Science, Imperial University of Tokyo, Japan = 東京帝國大學紀要. 理科 巻 27, p. 1-16, 発行日 1909-06-15 |
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| 書誌レコードID | ||||||
| 収録物識別子タイプ | NCID | |||||
| 収録物識別子 | AA00695779 | |||||
| フォーマット | ||||||
| 内容記述タイプ | Other | |||||
| 内容記述 | application/pdf | |||||
| 日本十進分類法 | ||||||
| 主題Scheme | NDC | |||||
| 主題 | 437.3 | |||||
| 出版者 | ||||||
| 出版者 | College of Science, Imperial University | |||||
| 出版者別名 | ||||||
| 東京帝國大學理學部 | ||||||
