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  1. 113 工学系研究科・工学部
  2. 38 化学システム工学専攻
  3. 1133810 学術雑誌論文
  1. 0 資料タイプ別
  2. 10 学術雑誌論文
  3. 014 自然科学

A new insight into the growth mode of metals on TiO2(110)

http://hdl.handle.net/2261/12
7ddcb5b8-32fc-4e5d-8e02-e270d700244f
名前 / ファイル ライセンス アクション
2002SS_hu.pdf 2002SS_hu.pdf (247.5 kB)
Item type 学術雑誌論文 / Journal Article(1)
公開日 2006-02-01
タイトル
タイトル A new insight into the growth mode of metals on TiO2(110)
言語
言語 eng
キーワード
主題 Growth
主題Scheme Other
キーワード
主題 Single crystal surfaces
主題Scheme Other
キーワード
主題 Titanium oxide
主題Scheme Other
キーワード
主題 Metallic films
主題Scheme Other
キーワード
主題 Surface chemical reaction
主題Scheme Other
キーワード
主題 Wetting
主題Scheme Other
資源タイプ
資源 http://purl.org/coar/resource_type/c_6501
タイプ journal article
著者 Hu, Minghui

× Hu, Minghui

WEKO 1

Hu, Minghui

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Noda, Suguru

× Noda, Suguru

WEKO 2

Noda, Suguru

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Komiyama, Hiroshi

× Komiyama, Hiroshi

WEKO 3

Komiyama, Hiroshi

Search repository
著者別名
識別子
識別子 4
識別子Scheme WEKO
姓名
姓名 野田, 優
著者別名
識別子
識別子 5
識別子Scheme WEKO
姓名
姓名 小宮山, 宏
抄録
内容記述タイプ Abstract
内容記述 The growth of metals on TiO2(1 1 0) at one monolayer coverage is classified into three-dimensional island, two-dimensional layer, and transition growth zones via two thermodynamic parameters, the heat of formation of metal oxides, −ΔfH0oxideofM, and the heat of sublimation of metals, −ΔfH0metal,permolofmetal (both expressed per mol of metal), which are easily obtainable. These two parameters represent the strength of metal/TiO2(1 1 0) interfacial interactions and the strength of metal/metal lateral interactions, respectively. Such classification is based on the thermodynamic criteria that the growth mode of metals on TiO2(1 1 0) is determined by metal/TiO2 interfacial free energy and metal surface free energy. Compared with the conventional approach that only uses the heat of formation of metal oxides, −ΔfH0oxideofO (expressed per mol of oxygen), our model provides a clearer and more comprehensive vision of the growth mode of metals on TiO2(1 1 0) and the factors affecting the growth mode. The approach described in this study can also be applied to other metal/reducible oxide systems.
書誌情報 Surface science

巻 513, 号 3, p. 530-538, 発行日 2002-08-01
ISSN
収録物識別子タイプ ISSN
収録物識別子 00396028
書誌レコードID
収録物識別子タイプ NCID
収録物識別子 AA00853803
フォーマット
内容記述タイプ Other
内容記述 application/pdf
日本十進分類法
主題 431.86
主題Scheme NDC
出版者
出版者 Elsevier
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