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A new insight into the growth mode of metals on TiO2(110)
http://hdl.handle.net/2261/12
7ddcb5b8-32fc-4e5d-8e02-e270d700244f
名前 / ファイル | ライセンス | アクション | |
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2006-02-01 | |||||
タイトル | ||||||
タイトル | A new insight into the growth mode of metals on TiO2(110) | |||||
言語 | ||||||
言語 | eng | |||||
キーワード | ||||||
主題 | Growth | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Single crystal surfaces | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Titanium oxide | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Metallic films | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Surface chemical reaction | |||||
主題Scheme | Other | |||||
キーワード | ||||||
主題 | Wetting | |||||
主題Scheme | Other | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Hu, Minghui
× Hu, Minghui× Noda, Suguru× Komiyama, Hiroshi |
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著者別名 | ||||||
識別子 | ||||||
識別子 | 4 | |||||
識別子Scheme | WEKO | |||||
姓名 | ||||||
姓名 | 野田, 優 | |||||
著者別名 | ||||||
識別子 | ||||||
識別子 | 5 | |||||
識別子Scheme | WEKO | |||||
姓名 | ||||||
姓名 | 小宮山, 宏 | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | The growth of metals on TiO2(1 1 0) at one monolayer coverage is classified into three-dimensional island, two-dimensional layer, and transition growth zones via two thermodynamic parameters, the heat of formation of metal oxides, −ΔfH0oxideofM, and the heat of sublimation of metals, −ΔfH0metal,permolofmetal (both expressed per mol of metal), which are easily obtainable. These two parameters represent the strength of metal/TiO2(1 1 0) interfacial interactions and the strength of metal/metal lateral interactions, respectively. Such classification is based on the thermodynamic criteria that the growth mode of metals on TiO2(1 1 0) is determined by metal/TiO2 interfacial free energy and metal surface free energy. Compared with the conventional approach that only uses the heat of formation of metal oxides, −ΔfH0oxideofO (expressed per mol of oxygen), our model provides a clearer and more comprehensive vision of the growth mode of metals on TiO2(1 1 0) and the factors affecting the growth mode. The approach described in this study can also be applied to other metal/reducible oxide systems. | |||||
書誌情報 |
Surface science 巻 513, 号 3, p. 530-538, 発行日 2002-08-01 |
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ISSN | ||||||
収録物識別子タイプ | ISSN | |||||
収録物識別子 | 00396028 | |||||
書誌レコードID | ||||||
収録物識別子タイプ | NCID | |||||
収録物識別子 | AA00853803 | |||||
フォーマット | ||||||
内容記述タイプ | Other | |||||
内容記述 | application/pdf | |||||
日本十進分類法 | ||||||
主題 | 431.86 | |||||
主題Scheme | NDC | |||||
出版者 | ||||||
出版者 | Elsevier |