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Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand
http://hdl.handle.net/2261/0002007598
http://hdl.handle.net/2261/0002007598ec186dd1-31e9-4c94-a040-8357a3902065
名前 / ファイル | ライセンス | アクション |
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acs_organomet2c00126.pdf (476.4 KB)
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© 2022 American Chemical Society
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Item type | 学術雑誌論文 / Journal Article(1) | |||||
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公開日 | 2023-06-20 | |||||
タイトル | ||||||
タイトル | Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand | |||||
言語 | en | |||||
言語 | ||||||
言語 | eng | |||||
資源タイプ | ||||||
資源 | http://purl.org/coar/resource_type/c_6501 | |||||
タイプ | journal article | |||||
著者 |
Seidel, Falk William
× Seidel, Falk William× Nozaki, Kyoko |
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著者所属 | ||||||
言語 | en | |||||
著者所属 | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo | |||||
抄録 | ||||||
内容記述タイプ | Abstract | |||||
内容記述 | We here report the oxidative addition of a hydroborane ligand to two low-valent Ir(I) precursors to furnish Ir(III) hydride complexes bearing a bidentate boryl/phosphine ligand. One cationic iridium complex easily displaces a THF and 1,5-COD supporting ligand by hydrogenation in benzene, to form a stable Ir(III) η⁶-benzene complex. The arene coordination thus gives insight into possible poisoning by arenes in catalytic reactions. | |||||
言語 | en | |||||
書誌情報 |
en : Organometallics 巻 41, 号 9, p. 1063-1066, 発行日 2022-04-21 |
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ISSN | ||||||
収録物識別子タイプ | PISSN | |||||
収録物識別子 | 02767333 | |||||
権利 | ||||||
権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright [© 2022 American Chemical Society] after peer review and technical editing by the publisher. To access the final edited and published work see [https://doi.org/10.1021/acs.organomet.2c00126]. | |||||
出版者 | ||||||
言語 | en | |||||
出版者 | American Chemical Society | |||||
関係URI | ||||||
関連タイプ | isVersionOf | |||||
識別子タイプ | URI | |||||
関連識別子 | https://doi.org/10.1021/acs.organomet.2c00126 | |||||
出版タイプ | ||||||
出版タイプ | AM |