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Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand
http://hdl.handle.net/2261/0002007598
http://hdl.handle.net/2261/0002007598ec186dd1-31e9-4c94-a040-8357a3902065
| 名前 / ファイル | ライセンス | アクション |
|---|---|---|
acs_organomet2c00126.pdf (476.4 KB)
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© 2022 American Chemical Society
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| Item type | 学術雑誌論文 / Journal Article(1) | |||||
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| 公開日 | 2023-06-20 | |||||
| タイトル | ||||||
| タイトル | Cationic and Neutral Iridium(III) Hydride Complexes Supported by a Rigid, Bidentate Boryl/Phosphine Ligand | |||||
| 言語 | en | |||||
| 言語 | ||||||
| 言語 | eng | |||||
| 資源タイプ | ||||||
| 資源 | http://purl.org/coar/resource_type/c_6501 | |||||
| タイプ | journal article | |||||
| 著者 |
Seidel, Falk William
× Seidel, Falk William× Nozaki, Kyoko |
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| 著者所属 | ||||||
| 言語 | en | |||||
| 著者所属 | Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo | |||||
| 抄録 | ||||||
| 内容記述タイプ | Abstract | |||||
| 内容記述 | We here report the oxidative addition of a hydroborane ligand to two low-valent Ir(I) precursors to furnish Ir(III) hydride complexes bearing a bidentate boryl/phosphine ligand. One cationic iridium complex easily displaces a THF and 1,5-COD supporting ligand by hydrogenation in benzene, to form a stable Ir(III) η⁶-benzene complex. The arene coordination thus gives insight into possible poisoning by arenes in catalytic reactions. | |||||
| 言語 | en | |||||
| 書誌情報 |
en : Organometallics 巻 41, 号 9, p. 1063-1066, 発行日 2022-04-21 |
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| ISSN | ||||||
| 収録物識別子タイプ | PISSN | |||||
| 収録物識別子 | 02767333 | |||||
| 権利 | ||||||
| 権利情報 | This document is the Accepted Manuscript version of a Published Work that appeared in final form in [Organometallics], copyright [© 2022 American Chemical Society] after peer review and technical editing by the publisher. To access the final edited and published work see [https://doi.org/10.1021/acs.organomet.2c00126]. | |||||
| 出版者 | ||||||
| 出版者 | American Chemical Society | |||||
| 言語 | en | |||||
| 関係URI | ||||||
| 関連タイプ | isVersionOf | |||||
| 識別子タイプ | URI | |||||
| 関連識別子 | https://doi.org/10.1021/acs.organomet.2c00126 | |||||
| 出版タイプ | ||||||
| 出版タイプ | AM | |||||
